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Volume 13 | Issue 3 | Year 2026 | Article Id. IJAES-V13I3P101 | DOI : https://doi.org/10.14445/23942568/IJAES-V13I3P101Optimization of Dye Waste Degradation Through Electrolysis with PbO2/Pb from Used Batteries
Sumarni, Eni Sabela, Sukmawati, Adam Saputera, Rian Erlangga Saputera, Nila Choirunayli, Sri Lestari
| Received | Revised | Accepted | Published |
|---|---|---|---|
| 10 Apr 2026 | 12 May 2026 | 28 May 2026 | 13 Jun 2026 |
Citation :
Sumarni, Eni Sabela, Sukmawati, Adam Saputera, Rian Erlangga Saputera, Nila Choirunayli, Sri Lestari, "Optimization of Dye Waste Degradation Through Electrolysis with PbO2/Pb from Used Batteries," International Journal of Agriculture & Environmental Science, vol. 13, no. 3, pp. 1-7, 2026. Crossref, https://doi.org/10.14445/23942568/IJAES-V13I3P101
Abstract
Chemical laboratories have a risk of danger due to the use of chemicals, including liquid waste that can pollute the environment. Laboratory liquid waste contains hazardous organic and inorganic compounds. One of the laboratory liquid wastes is dye waste. Waste treatment is important to reduce the negative impacts and hazards to health and the environment. One effective method for degrading dye waste is Electrodecolorization, an electrochemical process for degrading dyes using electric current. This method is able to degrade dye waste without producing new waste. This study aims to determine the optimization of the degradation of dye waste from the laboratory by electrolysis using PbO2/Pb electrodes from used batteries. This study was conducted by electrolyzing dye waste with variations in working potential, variations in electrolysis time, and variations in electrode distance. The absorbance of dye waste before and after electrolysis was measured using a UV-Vis Spectrophotometer at a wavelength of 330 nm. The results showed that the optimization of dye waste degradation occurred at a working potential of 6 V, electrolysis time of 90 minutes, and electrode distance of 1 cm.
Keywords
Degradation, Dye Waste, Electrodecolorization, Used Batteries, Electrolysis.
References
- Sri Mauludiyah et al., “Analysis of the Effectiveness of Laboratory Safety Procedures in Reducing the Risk of Chemical Accidents in the Chemistry Laboratory of Semarang State University,” Journal of Numbers, vol. 2, no. 1, pp. 134-151, 2025.
[Publisher Link] - Sabrina Nadillah, Sifa Nuraeni, and Rida Oktorida, “The Importance of Understanding the Hazards of Chemicals and their Relationship to Occupational Health and Safety in the Laboratory,” Journal of Medical Laboratory Analysis, vol. 7, no. 1, pp. 15-22, 2022.
[CrossRef] [Google Scholar] [Publisher Link] - Tia Amina Setiawati et al., “Documentation System for Management of Toxic and Hazardous Liquid Waste (B3) in Testing Services Laboratories,” Indonesian Journal of Laboratory, vol. 1, no. 2, pp. 41-48, 2019.
[CrossRef] [Google Scholar] [Publisher Link] - Shely Dwi Wulandari et al., “Biology Laboratory Waste Management in High School in Bantul Regency, yogyakarta,” Biology Didactics: Journal of Biology Education Research, vol. 6, no. 2, pp. 105-112, 2022.
[CrossRef] [Google Scholar] [Publisher Link] - Haryono Haryono, and Atiek Rostika, “Processing of Dispersed Textile Dye Waste using Electroflotation Method,” EduChemia: Journal of Chemistry and Education, vol. 3, no. 1, pp. 94-105, 2018.
[Google Scholar] - M. Indah, and P.S. Kimia, “Processing of Batik Dyestuff Waste in Waterways: Systematic Literature Review,” JSSIT (Journal of Science and Applied Science), vol. 2, no. 2, pp. 26-33, 2024.
[Google Scholar] - Sulistias Mustika, Abdul Haris, and Nor Basid Adiwibawa Prasetya, “Study of Electrophotocatalysis, Electrolysis and Photocatalysis Methods on the Decolorization of Remazol Black B Dye Solution Containing Cu2+ Metal Ions,” Journal of Scientific and Applied Chemistry, vol. 16, no. 1, pp. 17-22, 2013.
[CrossRef] [Google Scholar] [Publisher Link] - Baseem H. Fadhil, and Atheer M. Ghalib, “Electrochemical Decolorization of Direct Black Textile Dye Wastewater,” Journal of Engineering, vol. 17, no. 03, pp. 441-447, 2011.
[CrossRef] [Google Scholar] [Publisher Link] - Ina Triavia, Didik Setiyo Widodo, and Abdul Haris, “Electrodecolorization of Liquid Waste of Batik Dyes in Solo City with PbO2/Cu Electrodes,” Journal of Scientific and Applied Chemistry, vol. 19, no. 1, pp. 11-14, 2016.
[CrossRef] [Google Scholar] [Publisher Link] - Reviana Inda Dwi Suyatmo, and Hanifah Fitrah Putri Wiasih, “Degradation of Oxo-Degradable Plastic Bags and Polyethylene Waste using the Winogradsky Column Method,” Journal of Polymer Chemical Engineering and Technology, vol. 1, no. 1, pp. 23-32, 2024.
[CrossRef] [Google Scholar] [Publisher Link] - Didik Setiyo Widodo et al., “Potential Oxidative Treatment using Pb-PbO2 Electrode in Electrodecolorizing Batik Wastewater,” Journal of Scientific and Applied Chemistry, vol. 21, no. 3, pp. 118-123, 2018.
[CrossRef] [Google Scholar] [Publisher Link] - Ilyas Bacthiar, and Didik Setiyo Widodo, “Electrodecolorization of Textile Factory Wastewater in Semarang Area with PbO2/Pb Electrodes,” Journal of Scientific and Applied Chemistry, vol. 18, no. 3, pp. 85-90, 2015.
[CrossRef] [Google Scholar] [Publisher Link] - Yuchen Guo et al., “Advances on Water Quality Detection by UV-Vis Spectroscopy,” Applied Sciences, vol. 10, no. 19, pp. 1-18, 2020.
[CrossRef] [Google Scholar] [Publisher Link] - Syamsul Arifin et al., “The Relationship between Dissolved Organic Carbon and Soil Properties in Toposequences in Bukit Duabelas National Park,” Journal of Soil and Environmental Science, vol. 19, no. 2, pp. 51-59, 2017.
[CrossRef] [Google Scholar] [Publisher Link] - Fajri Rachmansyah, Satrio Budi Utomo, and Sumardi Sumardi, “Design and Implementation of Water Turbidity Measuring Instrument using Nephelometric Method in Water Treatment Plant with Multi Media Card (MMC) as Storage Media (Case Study at PDAM Jember),” Periodical Sainstek, vol. 2, no. 1, pp. 17-21, 2014.
[Google Scholar] - Haley A. Petersen et al., “Electrochemical Methods for Materials Recycling,” Materials Advances, vol. 2, no. 4, pp. 1113-1138, 2021.
[CrossRef] [Google Scholar] [Publisher Link] - Fera Friskaneke Menono, Teguh Wirawan, and Aman Sentosa Panggabean, “Electrodelocalization of Dye Substances in Samarinda Woven Gloves Liquid Waste using PbO2/Cu Electrodes,” Journal Atomik, vol. 9, no. 1, pp. 34-43, 2024.
[Google Scholar] [Publisher Link] - Didik Setriyo Widodo, Ismiyarto Ismiyarto, and Fithri Noorikhlas, “Electroremediation of Polluted Waters: 3. Electrodecolorization of Remazol Black B Solution with Lead Dioxide/Carbon Electrodes and Analysis of Residual Decolorization Solution,” Journal of Scientific and Applied Chemistry, vol. 12, no. 1, pp. 1-6, 2009.
[CrossRef] [Google Scholar] [Publisher Link] - Carlos A. Martínez-Huitle, and Sergio Ferro, “Electrochemical Oxidation of Organic Pollutants for the Wastewater Treatment: Direct and Indirect Processes,” Chemical Society Reviews, vol. 35, no. 12, pp. 1324-1340, 2006.
[CrossRef] [Google Scholar] [Publisher Link] - S. Bergaoui et al., “Electrosynthesis and Characterization of a Poly(Paraphenylene) Deriving from p-Fluoroanisole,” Electrochimica Acta, vol. 51, no. 20, pp. 4309-4315, 2006.
[CrossRef] [Google Scholar] [Publisher Link] - Jessica Margareta Jaya et al., “Sintesis Senyawa Etil Laurat Menggunakan Variasi Volume Katalis Asam Sulfat Pekat,” Journal Labora Medika, vol. 3, no. 1, pp. 1-9, 2019.
[Google Scholar] - Samia Saaidia et al., “Use of a PbO2 Electrode of a Lead-Acid Battery for the Electrochemical Degradation of Methylene Blue,” Separation Science and Technology, vol. 52, no. 9, pp. 1602-1614, 2017.
[CrossRef] [Google Scholar] [Publisher Link] - Mohammad Reza Samarghandi et al., “Electrochemical Degradation of Methylene Blue Dye using a Graphite Doped PbO2 Anode : Optimization of Operational Parameters, Degradation Pathway and Improving the Diodegradability of Textile Wastewater,” Arabian Journal of Chemistry, vol. 13, no. 8, pp. 6847-6864, 2020.
[CrossRef] [Google Scholar] [ Publisher Link] - Anggriana Novitasari, Rachmat Triandi, and Masruroh Masruroh, “Study of the Effect of Inter-Electrode Distance on Thin Phytocyanine Zinc Thin Layer Resistance (ZnPc) with Exposure to Ozone,” Natural B, Journal of Health and Environmental Sciences, vol. 3, no. 2, pp. 130-134, 2015.
[Google Scholar]