Investigation On The Influence of Varying Substrate Temperature On The Physical Features of Yttrium Doped Cadmium Selenide Thin Films Materials

International Journal of Applied Physics
© 2021 by SSRG - IJAP Journal
Volume 8 Issue 2
Year of Publication : 2021
Authors : Nwamaka I. Akpu, Asiegbu A.D, Nnanna L.A, Imosobomeh L. Ikhioya

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Nwamaka I. Akpu, Asiegbu A.D, Nnanna L.A, Imosobomeh L. Ikhioya, "Investigation On The Influence of Varying Substrate Temperature On The Physical Features of Yttrium Doped Cadmium Selenide Thin Films Materials," SSRG International Journal of Applied Physics, vol. 8,  no. 2, pp. 37-46, 2021. Crossref, https://doi.org/10.14445/23500301/IJAP-V8I2P106

Abstract:

The influence of varying substrate temperature on the structural, morphological, optical, and electrical properties of yttrium doped CdSe using the spray pyrolysis deposition method is reported in this work. The synthesized thin materials were characterized using X-ray diffraction-XRD, Scanning electron microscopy (SEM), Energy dispersive X-Ray (EDX), UV-Spectrophotometer, and Four-point probe. The XRD analysis revealed a polycrystalline hexagonal structure with the most preferred orientation along (100) plane for all the films irrespective of the substrate temperature. Y: CdSe deposited at 160oC gave the best crystallinity. The surface morphology ascertained using SEM shows uniform, well dense, and agglomerated films. The as-deposited films were homogenous devoid of cracks suggesting uniform deposition. The EDX results show the presence of the major elements i.e. Cd, Se, and Y which confirms the formation of CdSe and novel YCdSe thin particles. The optical results reveal that Y: CdSe deposited at 180oC exhibited better optical property when compared to other films with an energy bandgap value of 1.50eV. The electrical studies show that an increase in substrate temperature of the thin material decreases the resistivity with increasing thickness and increasing conductivity which reveals that the films are semiconducting material good for use in electronic and optoelectronic applications and more so for photovoltaic applications due to the narrowed bandgap.

Keywords:

Y- doped CdSe, substrate temperature, XRD, SEM, bandgap, optoelectronics

References:

[1] Deshpande M.P., N. Garg, S.V. Bhatt, P. Sakariya, S.H. Chaki, ( 2013) Characterization of CdSe thin films deposited by chemical bath solutions containing triethanolamine, Materials Science in Semiconductor Processing, 16 (2013) 915-922,
[2] Fujita A, A. Ota, K. Nakamura, Y. Nabetani, T. Kato, T. Matsumoto (2003) Luminescent properties of ZnCdSe/ZnMnSe superlattices, Materials Science in Semiconductor Processing, 6: 457-460
[3] Califano M., Zunger A. and Franceschetti A., (2004) Direct carrier multiplication due to inverse Auger scattering in CdSe quantum dots, Applied Physics Letters, 84:2409-2411
[4] Meulenberg RW, Buuren TV and Hanif KM (2004) Structure and Composition of Cu Doped CdSe Nanocrystals Using Soft Xray Absorption Spectroscopy. Nano Lett. 4: 2277p.
[5] Sivasankar J, P. Mallikarjuna P, Rao M.N, Kaleemulla S, Begam R.M and VenugopalRao G. (2017) Structural, Optical and Magnetic Properties of Cr Doped CdSe Powders Prepared by Solid State Reaction. Mechanics, Materials Science & Engineering journal.
[6] Pathak K.K., Pateria M.A, Deshmukh K and Jha P (2019) Effect of Sm concentration on optical and electrical properties of CdSe nanocrystalline thin film. Materials Science-Poland, 37(1), pp. 33-38:
[7] Yadav A.A., Barote M.A. and Masumdar E.U., (2010) Studies on cadmium selenide (CdSe) thin films deposited by spray pyrolysis, Materials Chemistry and Physics, 121:53-57,
[8] Xiaolei Qi, Xiaoping Zou, and Sheng He (2015) La Doping of CdS for Enhanced CdS/CdSe Quantum Dot Cosensitized Solar Cells. Hindawi Publishing Corporation. Journal of Chemistry Volume 2015, Article ID 710140, 7 pages
[9] Choudhary R and Chauhan R.P (2017) Swift Heavy Ion Induced Modifications in Optical and Electrical Properties of Cadmium Selenide Thin Films. Electron. Mater. Lett. pp. 1-9
[10] Rani S, Shanthi J, Kashif M, Ayeshamariam A and Jayachandran M (2016) Studies on Different Doped Zn Concentrations of CdSe Thin Films. Journal of Powder Metallurgy & Mining. Volume 5 issue 1
[11] Zhao Y., Yan Z., Liu J. and Wei A., (2013) Synthesis and characterization of CdSe nanocrystalline thin films deposited by chemical bath deposition, Materials Science in Semiconductor Processing, 16:1592-1598
[12] Singh S.B, Limaye M.V, Date S.K, Gokhale S and Kulkarni S.K (2009) iron substitute in CdSe nanoparticles: magnetic and optical properties. Physics review B, 80:235421
[13] Dangi D and Dhar R (2016) study of nonlinear optical properties of Fe doped CdSe nanoparticles. Journal of integrated Science and technology. Vol 4, No 1
[14] Aplop F. and Johan M.R (2014) Synthesis of Zn Doped CdSe Quantum Dots via Inverse Micelle Technique. Advance Material Science Enginerring Resourse Artical pp.1–4.
[15] Singh S.B, Limaye M.V, Lalla N.P and Kulkarni S.K (2008) copper-ion-induced photoluminescence tuning in CdSe nanoparticles. Journal of luminescence 128:1909-1912
[16] Vidhya R.D, Mary L.J and Jerome D.S, (2013) Synthesis and Characterization of 1-thioglycerol capped CdSe and Cu (copper) doped CdSe nanoparticles at Room Temperature. International Journal Chem Tech Res. 6(3):2042–2044pp.
[17] Kumar S, Kumari N, Kumar S, Jain S and Verma N.K (2012) Synthesis and characterization of Ni-doped CdSe nanoparticles: magnetic studies in 300–100 K temperature range, Applied Nanoscience. 2: 437–443p.
[18] Kwak WC and Sung YM (2007). Synthesis of Mn doped zinc blende CdSe nanocrystals. Appl phys Lett. 2007; 90: 173111
[19] Kushwaha K.K., Tiwary S.K., Vishwakarma N. and Choudhary Y. (2017) Doping of Metal Precursors on Cadmium Selenide Quantum dots—A Review. Journal of Nanoscience, Nanoengineering & Applications. Volume 7, Issue 3
[20] Osuwa J. C. and Chigbo N. I. (2012) Characterization of Structural And Electrical Properties of Electro-Deposited Cadmium Telluride (CdTe) Thin Films at Varying Deposition time On Glass FTO. Chalcogenide Letters Vol. 9, No. 12, December 2012, p. 501 – 508 pp 102-109
[21] Ikhioya I. L, Okoli D. N and Ekpunobi A. J (2019) Effect Of Temperature On SnZnSe Semiconductor Thin Films For Photovoltaic Application. SRG International Journal of Applied Physics (SSRG-IJAP) – Vol. 6, pp 55 – 67
[22] Jasim H.B (2014) Theoretical and Experimental Study for (CdSe) Nanoparticles. A PhD Thesis, College of Science University of Baghdad. 133pages
[23] Jeroh M.D, Ekpunobi A.J and Okoli D.N (2018) optical analytical studies of Electrostatic –sprayed Eu-doped Cadmium selenide nanofilms at different temperatures. Journal of nano and electronic physics volume 10 no 3
[24] Ikhioya I.L , Nkele A.C, Ezema S.N, Maaza M and Ezema F (2020) A study on the effects of varying concentrations on the properties of ytterbium-doped cobalt selenide thin films. Optical Materials vol. 10 pp. 19731
[25] Abhijit A.Y. (2014) Nanocrystalline copper selenide thin films by chemical spray pyrolysis. Journal of Mater Sci: Mater Electron, 25:1251–1257