Adsorption Isotherm And Kinetic Studies of Rhodamine B From Aqueous Solution Using Activated Carbon Prepared From Marigold Stems

International Journal of Applied Chemistry
© 2020 by SSRG - IJAC Journal
Volume 7 Issue 1
Year of Publication : 2020
Authors : I Made Siaka, Emmy Sahara
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How to Cite?

I Made Siaka, Emmy Sahara, "Adsorption Isotherm And Kinetic Studies of Rhodamine B From Aqueous Solution Using Activated Carbon Prepared From Marigold Stems," SSRG International Journal of Applied Chemistry, vol. 7,  no. 1, pp. 10-14, 2020. Crossref, https://doi.org/10.14445/23939133/IJAC-V7I1P103

Abstract:

This study explored the adsorption of rhodamine B by H3PO4 activated carbon prepared from marigold stems. The research aimed to evaluate various factors affecting the adsorption such as the contact time, adsorption isotherm, and pH. Moreover, the kinetics of the absorption of rhodamine B was also determined. The optimum conditions were then applied to the determination of rhodamine B adsorption capacity. The measurements of rhodamine B concentration were carried out by the use of UV-1800 Shimadzu spectrophotometer. It was evident that the optimum adsorption occurred at the equilibrium adsorption time of 90 minutes and pH 3 with the isotherm concentration of 120 mg/L, while the adsorption capacity was of 1.9205 mg/g. The rhodamine B adsorption the activated carbon follows the pattern of Langmuir isotherm. The adsorption kinetics patterns for the adsorption of rhodamine B follows the kinetics of second order with an adsorption rate constant of 3.00 x 10-5 min-1ppm-1.

Keywords:

activated carbon, adsorption, isotherm, kinetics, marigold stems, rhodamine B.

References:

[1] Badan Standardisasi Nasional of Indonesia, 1995, Karbon Aktif Teknis, SNI 06-3730-1995: Jakarta.
[2] Siaka, I M., Febriyanti, N. P. D., Sahara, E., and Negara, I M. S., 2016, Pembuatan dan Karakterisasi Karbon Aktif dari Batang Tanaman Gumitir (Tagetes erecta) pada Berbagai Suhu dan Waktu Pirolisis, Cakra Kimia (Indonesian EJournal of Applied Chemistry), 4(2): 168177.
[3] Sahara, E., Sulihingtyas, W. D., and Mahardika, I P. A. S., 2017, Pembuatan dan Karakterisasi Karbon Aktif dari Batang Tanaman Gumitir (Tagetes erecta) yang Diaktivasi dengan H3PO4, Jurnal Kimia, 11(1): 1-9.
[4] Sahara, E., Kartini, N. P. W., dan Sibarani, J., 2017, Pemanfaatan Karbon Aktif dari Limbah Tanaman Gumitir (Tagetes erecta) Teraktivasi Asam Fosfat sebagai Adsorben Ion Pb2+ dan Cu2+ dalam Larutan, Cakra Kimia (Indonesian E-Journal of Applied Chemistry), 5(2): 67-74.
[5] Siaka, I M. and Sahara, E., 2018, The Adsorption Kinetics of Cu(II) and Cr(III) by H3PO4 Activated Carbon Made from Marigold, International Journal of Current Advanced Research, 7(1): 8989-8993.
[6] Shresta, R. M., 2018, Adsorption Isotherm and Kinetic Studies of Cd (II) from Aqueous Solution Using Carbon Preared from Lapsi Seed Stone by Chemical Activation, International Journal of Advanced Engineering, 1(01): 16-22.
[7] Zhang, J. and Zhang , W., 2014, Preparation and Characteristics of Activated Carbon from Wood Bark and Its Use for Adsorption of Cu (II), Materials Science (MEDŽIAGOTYRA). 20(4).
[8] Bedmohata M.A., Chaudhari A.R., Singh S.P., and Choudhary M.D., 2015, Adsorption Capacity of Activated Carbon Prepared by Chemical Activation of Lignin for the Removal of Methylene Blue Dye. International Journal of Advanced Research in Chemical Science (IJARCS), 2(8): 1-13.
[9] Hesas, R. H., Arami-Niya, A., Daud, W. M. A. W., and Sahu, J. N., 2013, Preparation and Characterization of Activated Carbon from Apple Waste by Microwave-Assisted Phosphoric Acid Activation: Application in Methylene Blue Adsorption, BioResources 8(2): 2950-2966.
[10] Amri, N., Zakaria, R., and Bakar, M. Z. A., 2009, Adsorption of Phenol Using Activated Carbon Adsorbent from Waste Tyres, Pertanika J. Sci. & Technol, 17(2): 371 –380.
[11] Santhi, M. and Kumar, P. E., 2015, Adsorption of Rhodamine B from Aqueous Solution: Kinetic, Equilibrium and Thermodynamic Studies. International Journal of Innovation Research in Science. International Journal of Innovative Research in Sciences, Engineering and Technology, 4(2): 497-510.
[12] Jain, R., Mathur, M., Sikarwar, S., and Mittal, A., 2007, Removal of the Hazardous Dye Rhodamine B Through Photocatalytic and Adsorpyion Treatments, Journal of Environmental Management, 85: 956-964.
[13] Bhadusha, N. and Anantabaskaran, T., 2012, Kinetic Thermodynamic and Equilibrium Studies on Uptake of Rhodamine B onto ZnCl2 Activated Low Cost Carbon, EJournal of Chemistry, 9(1): 137-144.
[14] Kandisa, R. V., Saibaba KV, N., Shaik, K. B., and Gophinath, R., 2016, Dye Removal by Adsorption: A Review, Journal of Bioremediation and Biodegradation, 7(6).
[15] Ilayaraja, M., Krishnan, N. P., and Kannan R. S., 2013, Adsorption of Rhodamine-B and Congo Red Dye from Aqueous Solution: Kinetic, Isotherms and Thrmodynamics, IOSR Journal of Environmental Science, Toxicology and Food Technology, 5(5): 79-89.
[16] Kajjumba, G. W., Emik, S., Ongen, A., Ozcan, H. K., and Aydin, S., 2018, Modeling of Adsorption Kinetic Processes- Errors, Theory and Application. Available on URL file:///C:/Users/USER/Downloads/63161.pdf [cited on November 12th 2019].
[17] Roring, S. H., Pitoia, M. M., and Abidjulu J., 2013, Isoterm Adsorpsi Rhodamin B Pada Karbon Aktif Kayu Linggua, Jurnal MIPA Unsrat Online, 2(1): 40-43.
[18] Manocha, S. M., 2003, Porous Carbon, Sadhana, 28(1 & 2): 335-348.
[19] Subasri, S., Arivoli, S., Marimuthu, V., and Mani, N., 2015, Equilibrium, Kinetic and Thermodynamic Study on Rhodamine-B Removal from Aqueous Solution Using Activated Corchorus Olitorius-L Leaves, International Journal of Plant, Animal and Environmental Sciences, 5(1): 208-218.