Kinetic Isotherm of the Adsorption of Potassium Chloride on the Surfaces of Biochar Particles Prepared from the Solid Residues of the Olive Mill

International Journal of Agriculture & Environmental Science

© 2020 by SSRG - IJAES Journal

Volume 7 Issue 4

Year of Publication : 2020

Authors : Ali Zidan, Ali Muhammad Haider

10.14445/23942568/IJAES-V7I4P111

How to Cite?

Ali Zidan, Ali Muhammad Haider, "Kinetic Isotherm of the Adsorption of Potassium Chloride on the Surfaces of Biochar Particles Prepared from the Solid Residues of the Olive Mill," SSRG International Journal of Agriculture & Environmental Science, vol. 7,  no. 4, pp. 78-84, 2020. Crossref, https://doi.org/10.14445/23942568/IJAES-V7I4P111

Abstract:

The aim of this work, was to study the kinetics of adsorption of biochar particles prepared from the biomass of solid residues of the olive mill, in KCl solution, (KCl/BioC), system to be adopted to predict the default values of adsorption.
The experiment included the use of the biochar as a solid phase and source for adsorption surfaces in this system, where 3 equations were tested to model the resulted equilibrium data, in order to test their suitability for application in this system .
It was found that this adsorption kinetics isotherm follows a straight line positive relationship expressed very efficiently by first order equation, (R2 = 0.996), then Freundlich logarithmic equation (R2 = 0.968), within the limits of the experimental points of KCl concentrations in the liquid phase less than 60 meq/liter. But an application of a default secondorder equation for this system proved to be more expressive for all values of concentrations, where the correlation coefficient for this equation recorded high accuracy (R2 = 0.999), also it allows to predict any hypothetical value of adsorption for any KCl concentration in the solution including the maximum adsorption level.

Keywords:

Biochar, Adsorption, desorption, Olive mills, Freundlich, KCl/BioC system.

References:

[1] Lehmann J and S. Joseph. 2015. “Biochar for environmental management: sci. tech. and implementation”. Earthscan from Routledge, London 944 pp.
[2] Moreno-Castilla, C. 2004. “Adsorption of organic molecules from aqueous solutions on carbon materials”. Carbon 42:83–94.
[3] Martin SM, Kookana RS, Van Zwieten L and E. Krull. 2012. “Marked changes in herbicide sorptiondesorption upon ageing of biochars in soil”. J Hazard Mater 231–232:70–78.
[4] Ahmad M, Rajapaksha AU, Lim JE, Zhang M, Bolan N, Mohan D, Vithanage M, Lee SS, and YS. Ok. 2014. “Biochar as absorbent for contaminant management in soil and water: a review”. Chemosphere 99:19–33.
[5] Hu X, Ding Z, Zimmerman AR, Wang S and B. Gao. 2015. “Batch and column sorption of arsenic onto ironimpregnated biochar synthesized through hydrolysis”. Water Res 68:206–216.
[6] Novak JM, Busscher WJ, Laird DL, Ahmedna M, Watts DW and MA. Niandou. 2009. “Impact of biochar amendment on fertility of a southeastern coastal plain soil.” Soil Sci. 174: 105–112.
[7] Laird DA, Fleming P, Davis DD, Horton R,Wang BQ and DL. Karlen. 2010. “Impact of biochar amendments on the quality of a typical Midwestern agricultural soil”. Geoderma 158:443–449.
[8] Kloss S, Zehetner F, Dellantonio A, Hamid R, Ottner F, Liedtke V, Schawanni ngerM, Gerzabek MH and G. Soja. 2012. “Characterization of slow pyrolysis biochars: effects of feedstocks and pyrolysis temperature on biochar properties”. J Environ Qual 41:990–1000.
[9] Tang J, Zhu W, Kookana R and A. Katayama. 2013. “Characteristics of biochar and its application in remediation of contaminated soil.” J.Bio.sci.Bio.Eng. 116:653–659.
[10] Lehmann, J., Kern,D. C., Glaser, B and W. I. Woods. 2003. “Amazonian Dark Earths: Origin, Properties, Management”, Kluwer Academic Publishers", The Netherlands.
[11] Akhtar, S., Andersen, M and F. Liu. 2015. “Residual effects of biochar on improving growth, physiology and yield of wheat under salt stress”. Agricultural Water Management. 158. 61-68 .
[12] Mohan D, Pittman C Jr, Bricka M, Smith F, Yancey B, Mohammad J, Steele P, Alexandre-Franco M, Gómez-Serrano V and H. Gong. 2007. “Sorption of arsenic, cadmium, and lead by chars produced from fast pyrolysis of wood and bark during bio-oil production”. Journal of Colloid and Interface Science 310, 57–73.
[13] Hartley W, Dickinson N, Riby P and N. Lepp. 2009. “Arsenic mobility in brownfield soils amended with green waste compost or biochar and planted with Miscanthus. Environmental Pollution”. doi:10.1016/j.env. pol. 2009.05.011.
[14] Cheng C-H, Lehmann J and MH. Engelhard. 2009. “Natural oxidation of black carbon in soils:” Changes in molecular form and surface charge along a
climosequence. Geochimica et Cosmochimica Acta 72, 1598–1610 .
[15] Liang B, Lehmann J, Solomon D, Kinyangi J, Grossman J, et al. 2006. “Black carbon increases cation exchange capacity in soils”. Soil Science Society of America Journal 70, 1719–1730.
[16] Baldock JA and RJ. Smernik. 2002. “Chemical composition and bioavailability of thermally altered Pinus resinosa (Red pine) wood”. Organic
Geochemistry 33, 1093–1109 .
[17] Briggs C, Breiner JM and RC. Graham. 2012. “Physical and chemical properties of Pinus ponderosa charcoal”: implications for soil modification. Soil Science 177, 263–268 .
[18] Larsbo M, Lofstrand E, de Veer DA and B. Ulen. 2013. “Pesticide leaching from two Swedish top-soils of contrasting texture amended with biochar.” Journal of Contaminant Hydrology 147, 73–81 .
[19] Kishimoto, S. and G. Sugiura. 1985. ‘Charcoal as a soil conditioner’, in Symposium on Forest Products Research, International Achievements for the Future, vol 5, pp12–23
[20] Cheng, C. H., Lehmann, J., Thies, J. E and S.D. Burton. 2008. ‘Stability of black carbon in soils across a climatic gradient’, Journal of Geophysical Research, vol 113, G02027.
[21] Domingues RR, Trugilho PF, Silva CA, Melo I, Melo L, Magriotis ZM, et al. 2017. “Properties of biochar derived from wood and high-nutrient biomasses with the aim of agronomic and environmental benefits”. PLOS ONE 12(5): e0176884.
[22] Richards, L. A.1954. “Diagnosis and Improvement of Saline and Alkali Soils Handbook”. USDA. N0 60.
[23] Zamparas, M; M. Drosos,; Y. Georgiou; Y. Deligiannakis and I. Zacharias. 2013. “A novel bentonite-humic acid composite material Bephos™ for
removal of phosphate and ammonium from eutrophic waters.” Chemical Engineering Journal 225 (2013) 43–51 .
[24] Matar, A and A. Zidan. 1983. “THE MANUAL OF SOIL FERTILITY”. Text book for 4thyear agriculture. (Arabic). Pp 138, Tishreen University Publications. Syria.
[25] Gai, X., Wang, H., Liu, J., Zhai, L., Liu, Sh., Ren, T. and H. Liu. 2014. “Effects of feedstock and pyrolysis temperature on biochar adsorption of Ammonium and Nitrate.” Plose one. V: 9. Iss 12. e113888
[26] Askeland M, Clarke B and J Paz-Ferreiro. 2019. “Comparative characterization of biochars produced at three selected pyrolysis temperatures from common woody and herbaceous waste streams”. PeerJ, DOI 10.7717/peerj.6784.
[27] Mortvedt, J. J,. P. M. Giordano and W. L. Lindsay. 1982. “MICRONUTRIENTS IN AGRICULTURE”. 4thed, Soil Sc. Soc. of America, Inc. Madison,
Wisconsin USA.
[28] Udo, E. J., H. L. Bohn and T. C. Tucker. 1970. Zink adsorption by calcareous soils. Soil Sc. Soc. Amer. Proc. 34: 405 – 407 .
[29] Bangroo, S. A,. M. A. Wani,. T. Ali,. M. A. Malik,. N. A. Kirmani,. J. A. Sofi and F. Rasool. 2012. “Potassium adsorption characteristics of soils under long term maize-legume cropping sequence”. African Journal of Agricultural Research Vol. 7(48), pp. 6502-6507.
[30] Elrashidi, M. A and G. A. O'Connor. 1982. Boron Sorption and Desorption in Soils†. SSSA. Journal article no. 840, Agric. Exp. Stn., New Mexico State Univ., Las Cruces, NM 88003.
[31] I Made Siaka and Emmy Sahara ”Adsorption Isotherm And Kinetic Studies of Rhodamine B From Aqueous Solution Using Activated Carbon Prepared From Marigold Stems” SSRG International Journal of Applied Chemistry (SSRG-IJAC) – Volume 7 Issue 1 – Jan - April 2020.