Thermal and Physical properties of Lu3+ ions doped Zinc Lithium Tungsten Antimony Molybdate Glasses

International Journal of Applied Physics
© 2020 by SSRG - IJAP Journal
Volume 7 Issue 1
Year of Publication : 2020
Authors : S.L.Meena

pdf
How to Cite?

S.L.Meena, "Thermal and Physical properties of Lu3+ ions doped Zinc Lithium Tungsten Antimony Molybdate Glasses," SSRG International Journal of Applied Physics, vol. 7,  no. 1, pp. 43-48, 2020. Crossref, https://doi.org/10.14445/23500301/IJAP-V7I1P107

Abstract:

Zinc lithium tungsten antimony molybdate glasses containing Lu3+ in (45- x): Mo2O3: 10 ZnO: 10Li2O:10 WO3:25Sb2O3:xLu2O3 (where x=1, 1.5,2 mol %) have been prepared by melt-quenching method. The amorphous nature of the glasses was confirmed by Xray diffraction studies. The physical parameters like density, dielectric constant and electrical susceptibility have been evaluated. Dielectric constant, refractive index, electronic polarizability varies with increasing mole% of Lu2O3 respectively. The metallization criterion has been calculated on the basis of refractive index and energy gap. It was found to be decreased with increasing refractive index and decreasing energy gap. The large value of metallization criterion indicates that the glass materials are insulators.

Keywords:

Molybdenate based glass; Electrical Susceptibility; Metallization criterion

References:

[1] V .Dimitrov and T .Komatsu, “Classification of Simple Oxide: A Polarizability Approach,” Journal of Solid State Chemistry; 163(1), pp. 100-112 (2002).
[2] Kaminskii, A .Alexander , “Laser Crystals - Their Physics and properties”, Springer-Verlag, Berlin,pp. 20-40(1979).
[3] V. Dimitrov , S. Sakka, “Linear and nonlinear optical properties of simple oxides. II ”, J. Appl.Phys.,79,pp.1741-1745(1996).
[4] S.Takenaka, T.Tanaka, T. Funabiki and S.Yoshida, “Structures of Molybdenum Species in Silica-Supported Molybdenum Oxide and Alkali-Ion-Modified Silica-Sup- ported Molybdenum Oxide,” Journal of Physical Chem-istry B, Vol. 102, No. 16, pp. 2960-2969(1998).
[5] H. J. Borchardt and P. E. Bierstedt “Gd2(MoO4)3: A Ferroelectric Laser Host,” Applied Physics Letters, Vol. 8, No. 2, pp. 50-52(1996).
[6] S.Sudevan1 , T.Tilak1 , R. Mukherjee1 , A. Rajiv1 , M. S.Reddy1, Optical Properties of Lithium - Zinc – Boro- Molybdate Glass Doped with Rare Earth Oxides, IJCPS Vol. 4, No,-6, ISSN:2319-6602 (2015).
[7] N. F.Mott , E. A. Davis , “Electronic Processes in Non-Crystalline Materials”, Clarendon Press:Oxford Univ. Press, Oxford, pp. 437(1971).
[8] W.T.Carnall,P.R.Fields,K.Rajnak, “Electronic energy levels in the trivalent lanthanide aquo ions: Pr3+, Nd3+, Pm3+, Sm3+, Dy3+, Ho3+, Er3+ and Tm3+”, J. Chem.Phys., 49 (10), pp.4424-4442 (1968).
[9] M. M. Ahmed, C. A. Hogarth and M. N. Khan “A Study of the Electrical and Optical PropertiesoftheGeO2-TeO2 Glass System”, J. Mater. Sci. Lett., 19, pp. 4040-4044(1984).
[10] R.Subasri, D.Matusch, H. Näfe and F.Aldinger “Syn-thesis and Characterization of (La1-xMx)2Mo2O9-δ; M = Ca2+, Sr2+ or Ba2+,” Journal of the European Ceramic So-ciety, Vol. 24, No. 1, 2004pp. 129 137 (2004).
[11] Y.Ohishi, S.Mitachi, T. Kanamori and T. Manabe, Opticalabsorption of 3d transition metal and rare earth elements in zirconium fluoride glasses. Physics and Chemistry of Glasses, 24, 140(1983).
[12] J.E. Shelby and J.Ruller, Properties of Barium Gallium Germanate Glasses. Physics and Chemistry of Glasses, 28, 262(1987).
[13] M.J.Weber, Probabilities for Radiative and Nonradiative Decay of Er3+ in LaF3. Physical Review, 157, 272 (1967).
[14] X.Y. Zhao, X.L Wang, H.Lin, and Z.Q. Wang ,Electronic Polarizability and Optical Basicity of Lanthanide Oxides. Physica B, 392, 132 (2007).
[15] B.Bendow, P.K Benerjee, M.G. Drexhage, and Lucas, J. Journal of the American Ceramic Society, 65, C95, (1985).
[16] J.Schroeder, Brillouin, Scattering and Pockels Coefficients in Silicate Glasses. Journal of Non- Crystalline Solids, 40, 566 (1980).
[17] A.Klinokowski, Non-Monotonic Variations of Some Parameters in Vitreous R2O SiO2 and R2O Al2O3 SiO2 Systems. Journal of Non-Crystalline Solids, 72, 137 (1985).
[18] A.Shaker, A.Dasgupta, B. Babsu and A.Paul Journal of Materials Science Letters, 4, 697 (1983).
[19] M.M.Ahmed, C.A. Hogarth, and M.N. Khan, A Study of the Electrical and Optical Properties of the GeO2-TeO2 Glass System. Journal of Materials Science, 19, 4044(1984).
[20] P.Chimalawong, J.Kaewkhao, C.Kedkaew, and P.Limsuwan,Optical and ElectronicPolarizability Investigation of Nd3+-Doped Soda-Lime Silicate Glasses. Journal of Physics and Chemistry of Solids, 71,970(2010).
[21] D.Saritha, Y. Markandeya, M.Salagram, M. Vithal, A.K.Singh and G. Bhikshamaiah ,Effect of Bi2O3 on Physical, Optical and Structural Studies of ZnO-Bi2O3-B2O3 Glasses. Journal of Non-Crystalline Solids, 354, 5579 (2008).
[22] K.F. Herzfeld,On Atomic Properties Which Make an Element a Metal. Physical Review, 29, 705. (1927)
[23] M.S. Dresselhaus, Solid state physics part II: optical properties of solids, Proceedings Int. Sch. Phys., 198 (1966).