Experimental Study on the Production of One-Part Alkali-Activated Foam Mortar Containing Eggshell Waste

International Journal of Civil Engineering |
© 2025 by SSRG - IJCE Journal |
Volume 12 Issue 4 |
Year of Publication : 2025 |
Authors : Kübra Ekiz Barış |
How to Cite?
Kübra Ekiz Barış, "Experimental Study on the Production of One-Part Alkali-Activated Foam Mortar Containing Eggshell Waste," SSRG International Journal of Civil Engineering, vol. 12, no. 4, pp. 181-193, 2025. Crossref, https://doi.org/10.14445/23488352/IJCE-V12I4P117
Abstract:
Eggshell (ES) is an agro-based waste that produces alkali-activated materials. Although most of the research is focused on ES-based Alkali-Activated Mortars (AAM), Alkali-Activated Foam Mortars (AAFM) production is quite scarce. Using caustic aqueous alkaline solutions in traditional two-part mixing methods results in substantial dangers during large-scale applications. This study presents an opportunity to produce one-part AAFM, foamed with aluminum powder (Al), that uses metakaolin (MK) and ES as aluminosilicate precursors. The impacts of MK:ES and Al contents on the properties are researched. The highest density (D) (1.81 g/cm3), ultrasound velocity (UV) (2.33 km/s), Compressive Strength (CS) (12.50 MPa), and the lowest porosity (P) (15.35%), water absorption ratio (WAR) (9.82%), and Drying Shrinkage (DS) (511 μs), are detected in the samples with 70% of MK and 30% of ES. The pore size distributions change with Al content. Gradually increasing Al content to 1.50% results in an increase in the volume of macropores. The lowest thermal conductivity coefficient (TC), 0.187 W/mK, is determined in the (70MK:30ES)-1.50%Al sample. One-part AAFMs with various Al contents may be used as non-loadbearing wall materials, such as lightweight aggregate concrete, pumice concrete, aerated autoclaved concrete, and lightweight bricks.
Keywords:
Alkali activation, Eggshell waste, Foam mortar, One-part mixing method, Wall material.
References:
[1] Yun-Lin Liu et al., “Foaming Processes and Properties of Geopolymer Foam Concrete: Effect of the Activator,” Construction and Building Materials, vol. 391, 2023.
[CrossRef] [Google Scholar] [Publisher Link]
[2] Mohamed Abdellatief et al., “Physico-Mechanical, Thermal Insulation Properties, and Microstructure of Geopolymer Foam Concrete Containing Sawdust Ash and Egg Shell,” Journal of Building Engineering, vol. 90, 2024.
[CrossRef] [Google Scholar] [Publisher Link]
[3] Thammaros Pantongsuk et al., “Effect of Hydrogen Peroxide and Bagasse Ash Additions on Thermal Conductivity and Thermal Resistance of Geopolymer Foams,” Materials Today Communications, vol. 26, 2021.
[CrossRef] [Google Scholar] [Publisher Link]
[4] Peter Duxson et al., “The Role of Inorganic Polymer Technology in the Development of ‘Green Concrete’,” Cement and Concrete Research, vol. 37, no. 12, pp. 1590-1597, 2007.
[CrossRef] [Google Scholar] [Publisher Link]
[5] Junjie Feng et al., “Development of Porous Fly Ash-Based Geopolymer with Low Thermal Conductivity,” Materials & Design (1980-2015), vol. 65, pp. 529-533, 2015.
[CrossRef] [Google Scholar] [Publisher Link]
[6] Michał Łach et al., “Determination of the Influence of Hydraulic Additives on the Foaming Process and Stability of the Produced Geopolymer Foams,” Materials, vol. 14, no. 17, pp. 1-14, 2021.
[CrossRef] [Google Scholar] [Publisher Link]
[7] Viengsai Phavongkham et al., “Effects of Surfactant on Thermo-Mechanical Behavior of Geopolymer Foam Paste Made with Sodium Perborate Foaming Agent,” Construction and Building Materials, vol. 243, 2020.
[CrossRef] [Google Scholar] [Publisher Link]
[8] Joseph Henon et al., “Potassium Geopolymer Foams Made with Silica Fume Pore Forming Agent for Thermal Insulation,” Journal of Porous Materials, vol. 20, pp. 37-46, 2013.
[CrossRef] [Google Scholar] [Publisher Link]
[9] Yingjie Qiao et al., “Effects of Surfactants/Stabilizing Agents on The Micro-Structure and Properties of Porous Geopolymers by Direct Foaming,” Journal of Asian Ceramic Societies, vol. 9, no. 1, pp. 412-423, 2021.
[CrossRef] [Google Scholar] [Publisher Link]
[10] E. Kamseu et al., “Bulk Composition and Microstructure Dependence of Effective Thermal Conductivity of Porous Inorganic Polymer Cements,” Journal of European Ceramic Society, vol. 32, no. 8, pp. 1593-1603, 2012.
[CrossRef] [Google Scholar] [Publisher Link]
[11] Si Zou et al., “Experimental Research on an Innovative Sawdust Biomass-Based Insulation Material for Buildings,” Journal of Cleaner Production, vol. 260, 2020.
[CrossRef] [Google Scholar] [Publisher Link]
[12] Dilan Polat, and Mustafa Güden, “Processing and Characterization of Geopolymer and Sintered Geopolymer Foams of Waste Glass Powders,” Construction and Building Materials, vol. 300, 2021.
[CrossRef] [Google Scholar] [Publisher Link]
[13] Shu Yan et al., “Microstructure Evolution and Properties of Red Mud/Slag-Based Cenosphere/Geopolymer Foam Exposed to High Temperatures,” Ceramics International, vol. 49, no. 22, pp. 34362-34374, 2023.
[CrossRef] [Google Scholar] [Publisher Link]
[14] Review of Global Egg Production 2023, Compassion in Food Business, pp. 1-6, 2023. [Online]. Available: https://www.compassioninfoodbusiness.com/resources/laying-hens/review-of-global-egg-production-2023/
[15] A. Travel, Y. Nys, and M. Bain, Effect of Hen Age, Moult, Laying Environment and Egg Storage on Egg Quality, Improving the Safety and Quality of Eggs and Egg Products, Woodhead Publishing, pp. 300-329, 2011.
[CrossRef] [Google Scholar] [Publisher Link]
[16] Navaratnarajah Sathiparan, “Utilization Prospects of Eggshell Powder in Sustainable Construction Material – A Review,” Construction and Building Materials, vol. 293, 2021.
[CrossRef] [Google Scholar] [Publisher Link]
[17] Navdeep Singh, and S.P. Singh, “Validation of Carbonation Behavior of Self Compacting Concrete Made with Recycled Aggregates Using Microstructural and Crystallization Investigations,” European Journal of Environmental and Civil Engineering, vol. 24, no. 13, pp. 2187-2210, 2020.
[CrossRef] [Google Scholar] [Publisher Link]
[18] Poonam Shekhawat, Gunwant Sharma, and Rao Martand Singh, “Strength Behavior of Alkaline Activated Eggshell Powder and Fly Ash Geopolymer Cured at Ambient Temperature,” Construction and Building Materials, vol. 223, pp. 1112-1122, 2019.
[CrossRef] [Google Scholar] [Publisher Link]
[19] Vijayvenkatesh Chandrasekaran et al., “Experimental Investigation of Partial Replacement of Cement with Glass Powder and Eggshell Powder Ash in Concrete,” Civil Engineering Research Journal, vol. 5, no. 3, 2018.
[CrossRef] [Google Scholar] [Publisher Link]
[20] Ashfaque Ahmed Jhatial et al., “Green and Sustainable Concrete – The Potential Utilization of Rice Husk Ash and Egg Shells,” Civil Engineering Journal, vol. 5, no. 1, pp. 74-81, 2019.
[CrossRef] [Google Scholar] [Publisher Link]
[21] P. Shekhawat, G. Sharma, and R. M. Singh, “Microstructural and Morphological Development of Eggshell Powder and Flyash-Based Geopolymers,” Construction and Building Materials, vol. 260, 2020.
[CrossRef] [Google Scholar] [Publisher Link]
[22] Poonam Shekhawat, Gunwant Sharma, and Rao Martand Singh, “Morphology and Microstructure of Waste Material-Based Geopolymer with Flyash, Eggshell Powder, and Soft Soil,” Materials Letters, vol. 334, 2023.
[CrossRef] [Google Scholar] [Publisher Link]
[23] Arulanantham Anburuvel et al., “Characteristic Evaluation of Geopolymer Based Lateritic Soil Stabilization Enriched with Eggshell Ash and Rice Husk Ash for Road Construction: An Experimental Investigation,” Construction and Building Materials, vol. 387, 2023.
[CrossRef] [Google Scholar] [Publisher Link]
[24] M.O.M. Mashri et al., “Enhancing the Properties of UPOFA-Based Geopolymer Mortar via the Incorporation of Eggshell Ash and Silica Fume,” Journal of Building Engineering, vol. 65, 2023.
[CrossRef] [Google Scholar] [Publisher Link]
[25] Tarik Omur, Nausad Miyan, and Nihat Kabay, “Utilization of Eggshell Powder in One-Part Alkali-Activated Metakaolin Based Binder,” Construction and Building Materials, vol. 445, 2024.
[CrossRef] [Google Scholar] [Publisher Link]
[26] Xiongzhou Yuan et al., “Evaluation of The Performance of High- Strength Geopolymer Concrete Prepared with Recycled Coarse Aggregate Containing Eggshell Powder and Rice Husk Ash Cured at Different Curing Regimes,” Construction and Building Materials, vol. 434, 2024.
[CrossRef] [Google Scholar] [Publisher Link]
[27] Isabel Pol Segura et al., “Comparison of One-Part and Two-Part Alkali-Activated Metakaolin and Blast Furnace Slag,” Journal of Sustainable Metallurgy, vol. 8, pp. 1816-1830, 2022.
[CrossRef] [Google Scholar] [Publisher Link]
[28] Jie Ren et al., “Experimental Comparisons between One-Part and Normal (Two-Part) Alkali-Activated Slag Binders,” Construction and Building Materials, vol. 309, 2021.
[CrossRef] [Google Scholar] [Publisher Link]
[29] TS25, Data Sheet, Alldatasheet.Net. [Online]. Available: https://www.alldatasheet.net/view_datasheet.jsp?sSearchword=TS25&aPage=11&sField=3
[30] M.N. Freire, and J.N.F. Holanda, “Characterization of Avian Eggshell Waste Aiming Its Use in A Ceramic Wall Tile Paste,” Cerâmica, vol. 52, pp. 240-244, 2006.
[CrossRef] [Google Scholar] [Publisher Link]
[31] Ailar Hajimohammadi, Tuan Ngo, and Priyan Mendis, “How Does Aluminium Foaming Agent Impact The Geopolymer Formation Mechanism?,” Cement and Concrete Composites, vol. 80, pp. 277-286, 2017.
[CrossRef] [Google Scholar] [Publisher Link]
[32] TS-EN1015-10, Turkish Standard Institution, pp. 1-5, 2001. [Online]. Available: https://intweb.tse.org.tr/standard/standard/Standard.aspx?081118051115108051104119110104055047105102120088111043113104073081122083086079114097110065054057/
[33] TS-EN13755, Turkish Standard Institution, pp. 1-10, 2009. [Online]. Available: https://intweb.tse.org.tr/Standard/Standard/Standard.aspx?081118051115108051104119110104055047105102120088111043113104073102077043081050079068102067073056/
[34] TS699, Turkish Standard Institution, pp. 1-42, 2009. [Online]. Available: https://www.jmo.org.tr/resimler/ekler/596097c2f3799b4_ek.pdf/
[35] TS-EN1920-8, Data Sheet, Alldatasheet.Net. [Online]. Available: https://www.alldatasheet.net/view_datasheet.jsp?Searchword=TS-EN1920-8
[36] ASTM-C518-17, ASTM International. [Online]. Available: https://intweb.tse.org.tr/Standard/Standard/Standard.aspx?081118051115108051104119110104055047105102120088111043113104073102077043081050079068102067073056/
[37] TS-EN14579, Turkish Standard Institution, pp. 1-14, 2006. [Online]. Available: https://intweb.tse.org.tr/Standard/Standard/Standard.aspx?053107106111065067115113049116090107100056052055108081090071086075069085047110067109075073081116103090081086073108065117084119099101051071084104077111067108100082105053088112067066106067118112/
[38] TS-EN196-1, Turkish Standard Institution, pp. 1-31, 2009. [Online]. Available: https://intweb.tse.org.tr/standard/standard/Standard.aspx?081118051115108051104119110104055047105102120088111043113104073088066113082087078107067083069056/
[39] Alessandro Filipponi, Giulia Masi, and Maria Chiara Bignozzi, “Pressing Metakaolin-Based One-Part Geopolymers: Influence of the Mix Design on Microstructural and Physical Properties,” Ceramics International, vol. 48, no. 4, pp. 5814-5823, 2022.
[CrossRef] [Google Scholar] [Publisher Link]
[40] Kang-Wei Lo et al., “Synthesis Metakaolin-Based Geopolymer Incorporated with SIC Sludge using Design of Experiment Method,” Polymers, vol. 14, no. 16, pp. 1-13, 2022.
[CrossRef] [Google Scholar] [Publisher Link]
[41] C.K. Yip et al., “The Coexistence of Geopolymeric Gel and Calcium Silicate Hydrate at the Early Stage of Alkaline Activation,” Cement and Concrete Research, vol. 35, no. 9, pp. 1688-1697, 2005.
[CrossRef] [Google Scholar] [Publisher Link]
[42] Christina K. Yip et al., “Carbonate Mineral Addition to Metakaolin-Based Geopolymers,” Cement and Concrete Composites, vol. 30, no. 10, pp. 979-985, 2008.
[CrossRef] [Google Scholar] [Publisher Link]
[43] Deluan Feng et al., “Experimental Study on Preparation of Fly Ash-Based Geopolymer Blended with Recycled Calcium Source,” Sustainable Materials and Technologies, vol. 41, 2024.
[CrossRef] [Google Scholar] [Publisher Link]
[44] Ailar Hajimohammadi, Tuan Ngo, and Alireza Kashani, “Sustainable One-Part Geopolymer Foams with Glass Fines Versus Sand as Aggregates,” Construction and Building Materials, vol. 171, pp. 223-231, 2018.
[CrossRef] [Google Scholar] [Publisher Link]
[45] Adem Ahıskalı et al., “Mechanical and Durability Properties of Polymer Fiber Reinforced One-Part Foam Geopolymer Concrete: A Sustainable Strategy for The Recycling of Waste Steel Slag Aggregate and Fly Ash,” Construction and Building Materials, vol. 440, 2024.
[CrossRef] [Google Scholar] [Publisher Link]
[46] P. Chindaprasirt, S. Homwuttiwong, and V. Sirivivatnanon, “Influence of Fly Ash Fineness on Strength, Drying Shrinkage and Sulfate Resistance of Blended Cement Mortar,” Cement and Concrete Research, vol. 34, no. 7, pp. 1087-1092, 2004.
[CrossRef] [Google Scholar] [Publisher Link]
[47] D. Kioupis et al., “Development of Porous Geopolymers Foamed by Aluminum and Zinc Powders,” Ceramics International, vol. 47, no. 18, pp. 26280-26292, 2021.
[CrossRef] [Google Scholar] [Publisher Link]
[48] Fazel Azarhomayun et al., “Effect of Calcium Stearate and Aluminum Powder on Free and Restrained Drying Shrinkage, Crack Characteristic and Mechanical Properties of Concrete,” Cement and Concrete Composites, vol. 125, pp. 1-12, 2022.
[CrossRef] [Google Scholar] [Publisher Link]
[49] Shengwei Shen et al., “Synthesis of Industrial Solid Wastes Based Geopolymer Foams for Building Energy Conservation: Effects of Metallic Aluminium and Reclaimed Materials,” Construction and Building Materials, vol. 328, 2022.
[CrossRef]
[Google Scholar] [Publisher Link]
[50] Shikun Chen et al., “Pore Structure of Geopolymer Materials and Its Correlations to Engineering Properties: A Review,” Construction and Building Materials, vol. 328, 2022.
[CrossRef] [Google Scholar] [Publisher Link]
[51] TS825, Data Sheet, Alldatasheet.Net. [Online]. Available: https://www.alldatasheet.net/view_datasheet.jsp?Searchword=TS825
[52] Rui M. Novais et al., “Porous Biomass Fly Ash-Based Geopolymers with Tailored Thermal Conductivity,” Journal of Cleaner Production, vol. 119, pp. 99-107, 2016.
[CrossRef] [Google Scholar] [Publisher Link]