Mechanical Behavior of Glass Fiber-Reinforced Polyphenylene Sulfide with Carbon Nanofiber Additions

International Journal of Mechanical Engineering
© 2025 by SSRG - IJME Journal
Volume 12 Issue 8
Year of Publication : 2025
Authors : Arun Y C, Ravishankar R, Mahesh V M, Suresha B
pdf
How to Cite?

Arun Y C, Ravishankar R, Mahesh V M, Suresha B, "Mechanical Behavior of Glass Fiber-Reinforced Polyphenylene Sulfide with Carbon Nanofiber Additions," SSRG International Journal of Mechanical Engineering, vol. 12,  no. 8, pp. 50-60, 2025. Crossref, https://doi.org/10.14445/23488360/IJME-V12I8P106

Abstract:

This study systematically investigates the impact of Carbon Nanofiber (CNF) incorporation on the mechanical behavior of Glass Fiber-Reinforced Polyphenylene Sulfide (GF/PPS) composites. Tensile, flexural, and impact tests were conducted on composite samples with CNF loadings ranging from 0.2 wt% to 1.0 wt%, following ASTM standards to quantify the resulting changes in mechanical properties. According to tensile tests, adding 0.8 wt% CNF greatly increased stiffness, increasing tensile modulus by 11.1% and tensile strength by 4.6%. With the same CNF loading, flexural testing also showed significant gains, with a 27.2% increase in flexural modulus and a 19.5% increase in flexural strength. Scanning Electron Microscopy (SEM) sheds light on the mechanisms of failure. Furthermore, the tensile and flexural properties of GF/PPS composites are successfully improved by the selective addition of CNFs, especially at optimal concentrations, making these hybrid materials excellent choices for demanding structural engineering applications. However, the addition of CNF to GF/PPS reduced impact strength while increasing stiffness and modulus. This could have occurred because the material’s ductility and toughness were diminished by the increased stiffness, which limited its capacity to absorb impact energy through deformation and might have caused fracture initiation and propagation rather than energy dissipation.

Keywords:

GF/PPS composite, Carbon nanofibers, Hybrid composites, Mechanical properties, Scanning Electron Microscopy.

References:

[1] Debdatta Ratna, and Bikash Chandra Chakraborty, Polymer Matrix Composite Materials: Structural and Functional Applications, De Gruyter, pp. 1-433, 2023.
[Google Scholar] [Publisher Link]
[2] Dilyus Chukov et al., “Structure, Mechanical and Thermal Properties of Polyphenylene Sulfide and Polysulfone Impregnated Carbon Fiber Composites,” Polymers, vol. 11, no. 4, pp. 1-16, 2019.
[CrossRef] [Google Scholar] [Publisher Link]
[3] Dong Liu et al., “Experimental Investigation of Carbon Fiber Reinforced Poly (Phenylene Sulfide) Composites Prepared Using a Double-Belt Press,” Composites Part B: Engineering, vol. 77, pp. 363-370, 2015.
[CrossRef] [Google Scholar] [Publisher Link]
[4] Liang Zhao et al., “High-Performance Polyphenylene Sulfide Composites with Ultra-High Content of Glass Fiber Fabrics,” Composites Part B: Engineering, vol. 174, 2019.
[CrossRef] [Google Scholar] [Publisher Link]
[5] Sachin Sumathy Raj et al., “Philosophy of Selecting ASTM Standards for Mechanical Characterization of Polymers and Polymer Composites,” MaterialePlastice, vol. 58, no. 3, pp. 247-256, 2021.
[CrossRef] [Google Scholar] [Publisher Link]
[6] Jiangang Deng et al., “Thermal Aging Effects on the Mechanical Behavior of Glass-Fiber-Reinforced Polyphenylene Sulfide Composites,” Polymers, vol. 14, no. 7, pp. 1-11, 2022.
[CrossRef] [Google Scholar] [Publisher Link]
[7] Peiyuan Zuo et al., “Effect of Thermal Aging on Crystallization Behaviors and Dynamic Mechanical Properties of Glass Fiber Reinforced Polyphenylene Sulfide (PPS/GF) Composites,” Journal of Polymer Research, vol. 27, pp. 1-11, 2020.
[CrossRef] [Google Scholar] [Publisher Link]
[8] Shaofeng Zhou et al., “Effect of Carbon Fiber Reinforcement on the Mechanical and Tribological Properties of Polyamide6 / Polyphenylene Sulfide Composites,” Materials & Design, vol. 44, pp. 493-499, 2013.
[CrossRef] [Google Scholar] [Publisher Link]
[9] Basappa Hulugappa, Mysuru V. Achutha, and Bheemappa Suresha, “Effect of Fillers on Mechanical Properties and Fracture Toughness of Glass Fabric Reinforced Epoxy Composites,” Journal of Minerals and Materials Characterization and Engineering, vol. 4, no. 1, pp. 1-14, 2016.
[CrossRef] [Google Scholar] [Publisher Link]
[10] Guowei Chen et al., “Progress in Research and Applications of Polyphenylene Sulfide Blends and Composites with Carbons,” Composites Part B: Engineering, vol. 209, 2021.
[CrossRef] [Google Scholar] [Publisher Link]
[11] M.H. Cho, and S. Bahadur, “A Study of the Thermal, Dynamic Mechanical, and Tribological Properties of Polyphenylene Sulfide Composites Reinforced with Carbon Nanofibers,” Tribology Letters, vol. 25, pp. 237-245, 2007.
[CrossRef] [Google Scholar] [Publisher Link]
[12] Zhao Liu et al., “Effects of Polyarylene Sulfide Sulfone on the Mechanical Properties of Glass Fiber Cloth-Reinforced Polyphenylene Sulfide Composites,” High Performance Polymers, vol. 27, no. 2, pp. 145-152, 2015.
[CrossRef] [Google Scholar] [Publisher Link]
[13] Liang Zhao et al., “High-Performance Polyphenylene Sulfide Composites with Ultra-High Content of Glass Fiber Fabrics,” Composites Part B: Engineering, vol. 174, 2019.
[CrossRef] [Google Scholar] [Publisher Link]
[14] Ning Li et al., “Effect Fiber Length on Mechanical and Thermal Properties of Glass Fiber Reinforced Polyphenylene Sulfide Composite,” Journal of Reinforced Plastics and Composites, vol. 44, no. 15-16, pp. 902-912, 2024.
[CrossRef] [Google Scholar] [Publisher Link]
[15] Sridhar Doddalli Rudrappa, and Varadarajan Yellampalli Srinivasachar, “Significance of the Type of Reinforcement on the Physicomechanical Behavior of Short Glass Fiber and Short Carbon Fiber-Reinforced Polypropylene Composites,” Engineering Reports, vol. 2, no. 2, pp. 1-11, 2020.
[CrossRef] [Google Scholar] [Publisher Link]
[16] Shahzad Maqsood Khan et al., “Polyphenylene Sulphide / Carbon Fiber Composites: Study on Their Thermal, Mechanical and Microscopic Properties,” Iranian Polymer Journal, vol. 25, pp. 475-485, 2016.
[CrossRef] [Google Scholar] [Publisher Link]
[17] Bedriye U. Durmaz, and Ayse Aytac, “Characterization of Carbon Fiber-Reinforced Poly (Phenylene Sulfide) Composites Prepared with Various Compatibilizers,” Journal of Composite Materials, vol. 54, no. 1, pp. 89-100, 2019.
[CrossRef] [Google Scholar] [Publisher Link]
[18] Ana M. Díez-Pascual, and Mohammed Naffakh, “Inorganic Nanoparticle-Modified Poly (Phenylene Sulphide) / Carbon Fiber Laminates: Thermomechanical Behaviour,” Materials, vol. 6, no. 8, pp. 3171-3193, 2013.
[CrossRef] [Google Scholar] [Publisher Link]
[19] Nevin Gamze Karsli, Okan Gul, and Taner Yilmaz, “Investigation of the Synergistic Effect of Addition the Hybrid Carbon Fiber, Graphene Nanoplatelet and Matrix Modifier to Poly (Phenylene Sulphide) on Physical Properties,” Fibers and Polymers, vol. 23, no. 4, pp. 1059-1067, 2022.
[CrossRef] [Google Scholar] [Publisher Link]
[20] Bedriye Ucpinar, and Ayse Aytac, “Influence of Different Surface-Coated Carbon Fibers on the Properties of the Poly (Phenylene Sulfide) Composites,” Journal of Composite Materials, vol. 53, no. 8, pp. 1123-1132, 2019.
[CrossRef] [Google Scholar] [Publisher Link]
[21] F.A. Guimarães et al., “Mechanical Performance of Continuous/Short Carbon Fiber-Reinforced Poly (Phenylene Sulfide) Composites,” Engineering Failure Analysis, vol. 141, 2022.
[CrossRef] [Google Scholar] [Publisher Link]
[22] Tao Shi et al, “Research Progress on CNTs/CNFs-Modified Cement-Based Composites – A Review,” Construction and Building Materials, vol. 202, pp. 290-307, 2019.
[CrossRef] [Google Scholar] [Publisher Link]
[23] Ahmed Al-Sabagh et al, “Monitoring Damage Propagation in Glass Fiber Composites Using Carbon Nanofibers,” Nanomaterials, vol. 6, no. 9, pp. 1-12, 2016.
[CrossRef] [Google Scholar] [Publisher Link]
[24] Yanlei Wang et al, “Properties and Mechanisms of Self-Sensing Carbon Nanofibers/Epoxy Composites for Structural Health Monitoring,” Composite Structures, vol. 200, pp. 669-678, 2018.
[CrossRef] [Google Scholar] [Publisher Link]
[25] Michael Thomas Müller et al, “Online Structural-Health Monitoring of Glass Fiber-Reinforced Thermoplastics Using Different Carbon Allotropes in the Interphase,” Materials, vol. 11, no. 7, pp. 1-14, 2018.
[CrossRef] [Google Scholar] [Publisher Link]
[26] Selim Mrzljak et al, “Effect of Carbon Nanofibre Orientation on Fatigue Properties of Carbon Fibre-Reinforced Polymers,” Journal of Composite Materials, vol. 57, no. 6, pp. 1149-1164, 2023.
[CrossRef] [Google Scholar] [Publisher Link]
[27] Mohammed H. Al-Saleh, and Uttandaraman Sundararaj, “Review of the Mechanical Properties of Carbon Nanofiber/Polymer Composites,” Composites Part A: Applied Science and Manufacturing, vol. 42, no. 12, pp. 2126-2142, 2011.
[CrossRef] [Google Scholar] [Publisher Link]
[28] Alejandro J. Rodriguez et al., “Mechanical Properties of Carbon Nanofiber/Fiber-Reinforced Hierarchical Polymer Composites Manufactured with Multiscale-Reinforcement Fabrics,” Carbon, vol. 49, no. 3, pp. 937-948, 2011.
[CrossRef] [Google Scholar] [Publisher Link]
[29] M.E. Hossain et al., “Effect of Dispersion Conditions on the Thermal and Mechanical Properties of Carbon Nanofiber–Polyester Nanocomposites,” Journal of Engineering Materials and Technology, vol. 137, no. 3, pp. 1-9, 2015.
[CrossRef] [Google Scholar] [Publisher Link]
[30] Vijayakumar Nimbagal et al., “Mechanical and Fracture Properties of Carbon Nano Fibers/Short Carbon Fiber Epoxy Composites,” Polymer Composites, vol. 44, no. 7, pp. 3977-3989, 2023.
[CrossRef] [Google Scholar] [Publisher Link]
[31] J.I. Paredes, A. Martı́nez-Alonso, and J.M.D Tascón, “Surface Characterization of Submicron Vapor Grown Carbon Fibers by Scanning Tunneling Microscopy,” Carbon, vol. 39, no. 10, pp. 1575-1587, 2001.
[CrossRef] [Google Scholar] [Publisher Link]
[32] ASTM International, Standard Test Method for Tensile Properties of Plastics, ASTM International, 2022.
[Google Scholar] [Publisher Link]
[33] Standard Test Methods for Flexural Properties of Unreinforced and Reinforced Plastics and Electrical Insulating Materials, ASTM D790, Annual book of ASTM Standards, 1997.
[Google Scholar]
[34] Zoltán Major, Philipp S. Stelzer, and Florian Kiehas, Impact Loading and Testing, Characterization and Failure Analysis of Plastics, pp. 306-327, 2022.
[CrossRef] [Google Scholar] [Publisher Link]
[35] Lingda Shao et al., “Study on Preparation and Properties of Glass Fibre Fabric Reinforced Polyphenylene Sulphide Composites,” Materials, vol. 15, no. 24, pp. 1-14, 2022.
[CrossRef] [Google Scholar] [Publisher Link]
[36] Alen Oseli et al., “The Effect of Short Fiber Orientation on Long Term Shear Behavior of 40% Glass Fiber Reinforced Polyphenylene Sulfide,” Polymer Testing, vol. 81, 2020.
[CrossRef] [Google Scholar] [Publisher Link]
[37] Peiyuan Zuo et al., “Thermal Aging Effects on Overall Mechanical Behavior of Short Glass Fiber-Reinforced Polyphenylene Sulfide Composites,” Polymer Engineering & Science, vol. 59, no. 4, pp. 765-772, 2019.
[CrossRef] [Google Scholar] [Publisher Link]
[38] Ke Xu et al., “Enhanced Mechanical Properties of Polyphenylene Sulfide and Liquid Crystal Polymer Composites by Interfacial Bonding Capacity of Graft-Modified Graphene Oxide and Glass Fibers,” Polymers for Advanced Technologies, vol. 35, no. 4, 2024.
[CrossRef] [Google Scholar] [Publisher Link]
[39] Cristina Cazan, Alexandru Enesca, and Luminita Andronic, “Synergic Effect of TiO2 Filler on the Mechanical Properties of Polymer Nanocomposites,” Polymers, vol. 13, no. 12, pp. 1-24, 2021.
[CrossRef] [Google Scholar] [Publisher Link]
[40] SeungJae Ahn, Jae-Chul Lee, and Ki-Young Kim, “Preparation and Characterization of Glass-Fiber-Reinforced Modified Polyphenylene Oxide by a Direct Fiber Feeding Extrusion Process,” Applied Sciences, vol. 11, no. 21, pp. 1-13, 2021.
[CrossRef] [Google Scholar] [Publisher Link]
[41] J.Z. Liang, “Mechanical Properties of PPS/PC/GF/Nano-CaCO3 Hybrid Composites,” Polymer-Plastics Technology and Engineering, vol. 48, no. 3, pp. 292-296, 2009.
[CrossRef] [Google Scholar] [Publisher Link]
[42] Muhammad E. Hossain et al, “Low-Velocity Impact Behavior of CNF-Filled Glass-Reinforced Polyester Composites,” Journal of Composite Materials, vol. 48, no. 7, pp. 879-896, 2014.
[CrossRef] [Google Scholar] [Publisher Link]